If it is a CG1 functionspace, you can use
mesh.coordinates()
in combindation with
dof2vtx = vertex_to_dof_map(FunctionSpace(mesh, "CG" ,1))
for DOLFIN 1.2.0 or
dof2vtx = FunctionSpace(mesh,'CG',1).dofmap().vertex_to_dof_map(mesh).argsort()
for the development version.