Try something like this:
T = TensorFunctionSpace(mesh, "DG", 0)
sigma = project(sigma_w, T)
[s11, s12, s21, s22] = sigma.split(True)
print s11(PointA)
or:
T = TensorFunctionSpace(mesh, "DG", 0)
sigma = project(sigma_w, T)
print (sigma.sub(0))(pointA)